What are the recommended practices for storing sensors at low temperatures, and deploying at low temperatures or in frazil or pancake ice?
Large numbers of Sea-Bird conductivity instruments have been used in Arctic and Antarctic programs.
Special accommodation to keep temperature, conductivity, oxygen, and optical sensors at or above 0 C is advised. Often, the CTD is brought inside protective doors between casts to achieve this.
When freezing is possible, we recommend that the conductivity sensor be stored dry. Remove larger droplets of water by blowing through the cell. Do not use compressed air, which typically contains oil vapor. Attach a length of Tygon tubing to each end of the conductivity cell to close the cell ends. See Application Note 2D: Instructions for Care and Cleaning of Conductivity Cells for details.
There are several considerations to weigh when contemplating deployments at low temperatures in general, and in frazil or pancake ice:
- Ensure that the instrument is at or above water temperature before it is deployed. If the cell gets colder than 0 to -2 ºC while on deck, when it enters the water a layer of ice forms inside the cell as the cell warms to ocean temperature. If ice forms inside the conductivity cell, measurements will be low of correct until the ice layer melts and disappears. Thin layers of ice will not hurt the conductivity cell, but repeated ice formation on the electrodes will degrade the conductivity calibration (at levels of 0.001 to 0.020 psu) and thicker layers of ice can lead to glass fracture and permanent damage of the cell.
- For accurate measurements, keep ice out of the sensing region of the conductivity cell. The conductivity measurement involves determining the electrical resistance of the water inside the sensor. Ice is essentially a non-conductor. To the extent that ice displaces the water, the conductivity will register (very) misleadingly low. Some type of screening is necessary to keep ice out of the cell. This is relatively easy to arrange for the Sea-Bird conductivity cell, which is an electrode-type cell, because its sensing region is totally inside a long tube; plastic mesh could be positioned at each end and would have zero effect on accuracy and stability.
The above considerations apply to all known conductivity sensor types, whether electrode or inductive types.
If deploying at low temperatures but no surface frazil or pancake ice is present, rinse the conductivity cell in one of the following salty solutions (salty water depresses the freezing point) to prevent freezing during deployment. But this does not mean you can store the cell in one of these solutions outside . . . it will freeze.
- Solution of 1% Triton in sterile seawater (use 0.5-micron filtered seawater or boiled seawater), or
- Brine solution (distilled seawater or homemade salt solution that is higher than 35 psu in salinity).
Note that there is still a risk of forming ice inside the conductivity cell if deploying through frazil or pancake ice on the surface, if the freezing point of the salt water is the same as the water temperature. Therefore, we recommend that you deploy the conductivity cell in a dry state for these deployments.
Commercially available alcohol or glycol antifreezes contain trace amounts of oils that will coat the conductivity cell and the electrodes, causing a calibration shift, and consequently result in errors in the data. Do not use alcohol or glycol in the conductivity cell.
In general, neither the accuracy of the temperature measurement nor the survival of the temperature sensor will be affected by ice.
For the SBE 43 and SBE 63 Dissolved Oxygen sensor, avoid prolonged exposure to freezing temperature, including during shipment. Do not store the with water (fresh or seawater), Triton solution, alcohol, or glycol in the plenum. The best precaution is to keep the sensor indoors or in some shelter out of the cold weather.